MERCon - 2015

Permanent URI for this collectionhttp://192.248.9.226/handle/123/14696

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Browsing MERCon - 2015 by Subject "Adsorption"

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    item: Conference-Abstract
    Adsorption of cadmium and lead heavy metals by Chitosan Biopolymer : a study on equilibrium Isotherms and kinetics
    Unagolla, JM; Adikary, SU
    Since heavy metal pollution is a significant aspect to aquatic ecosystems, the objective of this research work was to investigate adsorption characteristics of chitosan as an alternative adsorbent material. In this study, chitosan, synthesized from locally available shrimp type “penaeus monodon” was used to observe adsorption characteristics of cadmium (Cd) and lead (Pb) heavy metals from aqueous solution. Batch kinetic experiment studies were conducted for changing initial pH, initial concentration of metal ions, particle size and degree of deacetylation (DD) of chitosan. Simplified models such as, pseudo first order, pseudo second order and intra-particle diffusion models were used to analyze the experimental data. The result showed that the adsorption capacity strongly depends on pH and DD. It was clearly seen that higher adsorption of heavy metals occur at comparatively high pH and high DD. Equilibrium experimental data were analyzed by using two different isotherm models namely, Langmuir and Freundlich. The characteristic parameters for each isotherm and related correlation coefficients were determined by using mathematical modeling software. Isotherms show that adsorption process of Cd and Pb is a heterogeneous process.
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    item: Conference-Abstract
    Bio-methane adsorption by activated carbon understanding the potential via characterization of Sri Lankan activated carbon
    Herath, HMBM; De Alwis, AAP
    There is growing global interest on bio-methane as a vehicular fuel and Europe Union (EU) has stated that this as a best well-to-wheel fuel. Commercialization of bio-methane under atmospheric conditions is limited due to its requirement of higher storage capacity. Compressed bio-methane systems have been currently commercialized in Europe in order to increase its low energy density however the process requires higher capital and maintenance costs. Thus, adsorbed bio-methane is suggested as a better alternative to store methane under low pressure conditions & activated carbon (AC) has shown promise as a methane adsorbent. This study is based on identifying the potential absorptivity of bio-methane into commercially available AC in Sri Lanka. The paper presents the pathway envisage in this task. Two types of commercial AC samples as granular & pelletize forms have been used from supplier HAYCARB for the analysis. this paper, characterization data from the principals is used to investigate the methane uptake potential into commercial AC. Further, the study has been continued in evaluating several developed correlations in literature on linear behaviour of micropore volume of AC to methane uptake & concluded that the linear parameters of micropore volume to methane uptake would vary according to AC properties. Thus a correlation for local AC is important to be developed. Hence, an experimental setup is developed to carry out detailed studies on bio-methane adsorption on commercial AC available in Sri Lanka.