Browsing by Author "Sato, H"
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- item: Conference-Full-textCharacterization of landfill leach ate from municipal solid wastes landfills in Sri Lanka(2013-11-13) Sewwandi, BGN; Takahiro, K; Kawamoto, K; Hamamoto, S; Asamoto, S; Sato, HOpen dumping of municipal solid waste (MSW) is the most common way of handling solid waste in Sri Lanka due to high cost involved with advanced technologies for landfilling, lack of technical capacity, lack of know-how to manage landfill sites, and so on. Landfill leachate generated from the MSW landfill sites must be treated before dispose into the environment as it creates many social and environmental problems. Characterization of landfill leachate is important to identify the most critical pollutants present in the leachate and thereby to introduce suitable and applicable treatment technologies such as in-situ permeable reactive barrier technologies for contaminant remediation. Therefore, the objective of this research is to characterize landfill leachate collected from several MSW landfills in Sri Lanka. The leachate samples were collected from 12 landfill sites located in Matale, Hambantota, Kataragama, Bandaragama, Kolonnawa, Gampola, Gohagoda, Wennappuwa, Rathnapura, Negombo, Galle, and Matara. For the collected samples, general water quality parameters (pH, EC, DO, ORP, and SS), organic pollutants (BOD5, COD, TOC, IC, TN, TP), typical anions and cations (Cl-, SO42-, NH4+, K+, Mg2+, Ca2+, etc), and heavy metals (Cr, Mn, Fe, Se, Pb, etc) were measured. The results showed that most of the pollutants (F-, Cl-, PO43-, NH4+, Fe, Se, Pb, BOD5, and COD) exceeded the maximum tolerance limits in Sri Lankan Standards. It was found that the BOD5/COD ratio ranged from 0.01 to 0.6 for the most samples and the highest value of 0.6 was observed in the Kolonnawa sample. Measured EC values for all samples were high and varied ranging from 4.5 to 38.3 mS/cm, indicating the biological treatment system alone would not be effective in reducing the pollutants especially for heavy metals. The results of this study will be used in developing site specific remediation technologies in landfill leachate treatment.
- item: Conference-AbstractKey factors of metastable phase formation for strength development in steel slag and dredged soil mixturesToda, K; Otake, T; Sato, T; Sato, H; Weerakoon, N; Nishimura, SThe usage of by-products from industrial activities, as construction resources is awaited in Japan to decrease the environmental impacts. Steel slag from iron works and dredged soil extracted beneath the ports are examples for such resources. Recently, it is discovered that mixtures of steel slag with dredged soil are hardened. This discovery may expand their application into building materials for undersea construction which may solve the problem. Nonetheless, different combinations of a type of steel slag and dredged soil from various areas show gaps in strength development. The relationship between mixing condition and strength development is not clarified, making the mixture difficult to be utilized for the above application. Understanding of the hardening mechanism of the steel slag-dredged soil mixture would enable the prediction of the strength with a particular combination of steel slag and dredged soil. To achieve it, clarifying the secondary mineral formation that contributes to hardening is essential. Previous studies suggested that the strength development was related to the pozzolanic reaction, which results in cementation by the formation of calcium silicate hydrates (C-S-H). Key factors in the pozzolanic reaction are the increase in pH of the pore water and the supply of calcium and silica ions to pore water. While calcium supply is determined to be Ca(OH)2 in steel slag which also increases pH by its hydration, silica supply is only suggested to be originated in dredged soils. The objective of this study is set to understand the effects of silica-bearing phases in dredged soil on the strength development of steel slag-dredged soil mixture. In this study, dredged soils from various sampling locations (A, B, C and D) and steel slag from ironworks-1 were mixed for the investigation. The unconfined compressive strength showed mixtures with soil-A exhibits the highest strength, followed by those with B, C and D. Firstly, the silica ion which is most likely to be supplied from dredged soils was investigated. The biogenic silica content and inorganic amorphous silica such as volcanic glass content were quantified. XRD analysis showed no significant difference between the mineralogical compositions of all the dredged soils including clay minerals. Then, the effect of humic acid which may limit the supply of soluble calcium is quantified and its functional groups are analysed to see the effect on strength development of the mixtures. Through geochemical modeling for estimation of C-S-H formed from above silica supply, we suggest that the silica supply from each silica-bearing phase of dredged soils may be the driving force for the pozzolanic reaction for the strength development.
- item: Conference Full-textKey factors of metastable phase formation for strength development in steel slag and dredged soil mixturesToda, K; Otake, T; Sato, T; Sato, H; Weerakoon, N; Nishimura, S; ; Abeysinghe, AMKB; Dassanayake, ABN; Elakneswaran, Y.;The usage of by-products from industrial activities, as construction resources is awaited in Japan to decrease the environmental impacts. Steel slag from ironworks and dredged soil extracted beneath the ports are examples for such resources. Recently, it is discovered that mixtures of steel slag with dredged soil are hardened. This discovery may expand their application into building materials for undersea construction which may solve the problem. Nonetheless, different combinations of a type of steel slag and dredged soil from various areas show gaps in strength development. The relationship between mixing condition and strength development is not clarified, making the mixture difficult to be utilized for the above application. Understanding of the hardening mechanism of the steel slag-dredged soil mixture would enable the prediction of the strength with a particular combination of steel slag and dredged soil. To achieve it, clarifying the secondary mineral formation that contributes to hardening is essential. Previous studies suggested that the strength development was related to the pozzolanic reaction, which results in cementation by the formation of calcium silicate hydrates (C-S-H). Key factors in the pozzolanic reaction are the increase in pH of the pore water and the supply of calcium and silica ions to pore water. While calcium supply is determined to be Ca(OH)2 in steel slag which also increases pH by its hydration, silica supply is only suggested to be originated in dredged soils. The objective of this study is set to understand the effects of silica-bearing phases in dredged soil on the strength development of steel slag-dredged soil mixture. In this study, dredged soils from various sampling locations (A, B, C and D) and steel slag from ironworks-1 were mixed for the investigation. The unconfined compressive strength showed mixtures with soil-A exhibits the highest strength, followed by those with B, C and D. Firstly, the silica ion which is most likely to be supplied from dredged soils was investigated. The biogenic silica content and inorganic amorphous silica such as volcanic glass content were quantified. XRD analysis showed no significant difference between the mineralogical compositions of all the dredged soils including clay minerals. Then, the effect of humic acid which may limit the supply of soluble calcium is quantified and its functional groups are analysed to see the effect on strength development of the mixtures. Through geochemical modeling for estimation of C-S-H formed from above silica supply, we suggest that the silica supply from each silica-bearing phase of dredged soils may be the driving force for the pozzolanic reaction for the strength development.