ISERME - 2024

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Browsing ISERME - 2024 by Author "Abeysinghe, AMKB"

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    Exploration and characterization of potential iron ore occurrence in Pelpitigoda, Sri Lanka
    (Division of Sustainable Resources Engineering, Hokkaido University, Japan, 2024) Wijethunge, HP; Appuhamy, RPMC; Vilojan, M; Ratnayake, NP; Abeysinghe, AMKB; Premasiri, HMR; Rohitha, LPS; Dushyantha, NP; Batapola, NM; Dilshara, RMP; Iresha, H; Elakneswaran, Y; Dassanayake, A; Jayawardena, C
    Iron is widely used across industries in worldwide, with an annual usage of over 1.8 billion tonnes, steadily increasing over decades. Due to this high consumption of iron, it is crucial to find new sources of iron. Therefore, this research project was designed with the objectives of exploring the potential iron occurrence and characterize the mineralogy and geochemistry of the Pelpitigoda area. The methodology comprises two phases. In the initial phase, geological settings were studied to understand the rock formations and structures surrounding the area. It was followed by a magnetic susceptibility survey to identify variations and anomalies, along with systematic sample collection across the deposit. The phase two was completed with laboratory analysis, including sample preparation, colorimetry, X-ray Diffraction (XRD), X-ray Fluorescence (XRF), and Inductively Coupled Plasma Mass Spectrometry (ICP-MS). Notably, colorimetry results from phase two indicated iron content ranging between 40-60 wt% in the samples, with XRD analysis identifying goethite as the predominant mineral, alongside magnetite, hematite, and gibbsite. XRF results revealed an average iron content of 38.47 wt%. Furthermore, ICP-MS analysis showed lower potential for valuable metals like V, Cr, Co, Ni, and Zn in the area. The significance of this research lies in its potential to identify a new iron ore occurrence in the Pelpitigoda area. The comprehensive characterization of the mineralogy and geochemistry provides valuable insights into the composition and distribution of iron-bearing minerals in the area. Future work entails completing the last phase of roasting the samples to extract iron oxide, followed by comprehensive laboratory testing of the prepared samples.
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    Extraction potential of nickel from native hyperaccumulator plants from Ginigalpelessa serpentinite deposit
    (Department of Architecture University of Moratuwa, 2024) Dilshara, RMP; Abeysinghe, AMKB; Premasiri, HMR; Ratnayake, NP; Senarath, WTPSK; Ratnayake, AS; Dushyantha, NP; Batapola, NM; Iresha, H; Elakneswaran, Y; Dassanayake, A; Jayawardena, C
    Serpentine soils are low-grade Ni resources that have been utilized widely to extract Ni to meet its burgeoning demand in the renewable energy sector. However, the economic impracticability of Ni recovery by conventional mining techniques has been directed towards Ni phytomining, in which native hyperaccumulators grown in serpentine soils are used for commercial Ni recovery. In this context, the Ginigalpelessa serpentinite deposit in Sri Lanka harbors a wide variety of plants that can accumulate high Ni concentrations from the soil. Despite the promising Ni potential (0.4-1.7%) in the Ginigalpelessa serpentinite deposit, the lack of detailed studies on the hyperaccumulation ability of native plant species and proper extraction methods retards the commercial application of Ni phytomining in this deposit. Therefore, the present study carried out ex-situ phytomining trials using two native hyperaccumulator species namely, Crotalaria verrucosa and Apluda mutica. The harvested biomasses were then incinerated to produce Ni-rich bio-ores, which were analyzed for Ni concentration using Inductively Coupled Plasma Mass Spectrometer (ICP-MS). The bio-ore of C. verrucosa contained 7,279 ± 106 mg/kg of Ni whereas the bio-ore of A. mutica showed 3,867 ± 39 mg/kg of Ni. The bio-ore of A. mutica was used for the leaching experiments due to its highest abundance in the deposit. The leaching assays were carried out with A. mutica bio-ore under different pulp densities (100 g/L and 200 g/L) and H2SO4 concentrations (1 mol/L and 5 mol/L). The bio-ores used in leaching experiments were produced from an open flame and muffle furnace (at 550 ⁰C). The highest leaching efficiency was observed as 59% in open burnt samples (leachate Ni concentration = 649 mg/kg and total Ni concentration = 1,098 mg/kg) under 100 g/L pulp density and 5 mol/L H2SO4 concentration. The overall low leaching efficiency of bio-ore can be attributed to the formation of an aluminum silicate matrix (Al2O3.2SiO2) during leaching experiments which inhibits the Ni leaching. Therefore, the present study requires further investigations to optimize the leaching efficiency to implement a sustainable Ni extraction method for the local serpentinite bodies. Financial assistance from the Senate Research Committee, University of Moratuwa (Grant no: SRC/LT/2021/15) is acknowledged.